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THERMODYNAMIC TRANSPORT PHENOMENA

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  • DISSEMINATION AND SPREAD IN WAYS FRACTALS.
    Author: CAMPOS MORENO DANIEL.
    Year: 2004.
    University: AUTÓNOMA DE BARCELONA [www.uab.es].
    Place of defense: FACULTAT DE CIÈNCIES.
    Place of preparation: ESCUELA DE POSTGRADO.
    Summary: This paper is intended to study and model the main features of the transport processes through media or autosimilares fractals. Despite being very different structures among themselves and seemingly irregular fractals have a number of common properties, which are typically characterized by laws of scale, and allowing pose a transport model. We, after reviewing the main results which are known in the field of broadcasting media fractals, we propose an analytical equation is able to explain almost all of these results and even predicts that some behavior is not known so far. The validity of this model is verified through simulations random-walk conducted on computer-generated fractal structures. Besides diffusion processes, we propose that the model can be extended to consider other transport phenomena more generally. Specifically, we devoted a portion of work to the study of reaction processes in ways fractals and, as these models lead to solutions for propagatorio, we concentrated especially in determining velocities of propagation model predicts that in such cases, new checking the validity of these results through simulations. The last part of the report is devoted to exploring practical applications and comparison with experiments in which the diffusion processes or propagation through media autosimilares may have special relevance. The specific applications under consideration are: 1 - The spread of substances through hydrographic networks. 2, - biological processes migration through networks fractals. 3 - The combustion processes and forest fires distributions in heterogeneous fuel. 4 - The spread of chemical fronts in ways fractals.
  • LIMITS OF VALIDITY OF THE THEORY FJO DETERMINATION OF DIFFUSION COEFFICIENTS OF LIQUID BINARY MIXTURES IN COLUMNS TERMOGRAVITACIONALES
    Author: VALENCIA MONREAL JOSE JAVIER.
    Year: 2004.
    University: PAÍS VASCO [www.ehu.es].
    Place of defense: FACULTAD DE CIENCIA Y TECNOLOGIA.
    Place of preparation: ESCUELA SUPERIOR DE INGENIEROS DE BILBAO.
    Summary: THE EQUATIONS TERMOHIDRODINÁMICAS GOVERNING THE PHENOMENON OF THE DISSEMINATION TERMICA SE SIMPLIFICAN THROUGH THE THEORY FURRY, JONES AND ONSANGER (FJO) GETTING RESULTS ANALYTICAL. HE PRODUCES AN AGENDA FOR CALCULATION USING THE METHOD IN DIFFERENCES FINITAS, AND THROUGH THE PARAMETERS ARE OBTAINED RELEVANT RESULTS NUMERICOS. THE PROGRAM COMES VALIDADO WITH THE BENCHMARK PROPOSED BY DAVIS VAHL. RESULTS NUMERICOS SE COMPARAN WITH FJO OBTAINED THROUGH THE THEORY AND ESTABLISHING THE LIMITS OF VALIDITY OF THIS THEORY. BASANDOSE IN THE OUTCOME OF THE THEORY FJO INTRODUCING THE CRITERIA FOR THE CONSTRUCTION OF COLUMNS OF TYPE CLUSIUS-DICKEL. SE CONTRUYEN COLUMNS TERMOGRAVITACIONALES IN STAINLESS STEEL TUBES WHOSE BEEN CAREFULLY SELECTED. IN THIS WAY, ARE OBTAINED COLUMNS TERMOGRAVITACIONALES THAT IF OPERATE WITHIN THE RANGE OF THE VALIDITY OF THEORY FJO, INSTRUMENTS ARE OUTSTANDING FOR GETTING THE COFICIENTES OF THE TRANSPORT OF LIQUID BINARIAS ORGANICAS MIXTURES. SE MIDEN THE RATES OF BROADCASTING AND THERMAL COEFFICIENTS OF BROADCASTING AND THEREFORE THE ORDINARY COEFFICIENT SORET OF THE FOLLOWING MIXTURES BINARIAS - TOLUENE / HEXANE (51.7%). - WATER / ETANOL (39.12%). - TETRALINA / DODECANO (50%). - TETRALINA / ISOBUTILBENCENO (50%). - ISOBUTILBENCENO / DODECANO (50%). - WATER / METANOL (90%). - WATER / ETANOL (90%). - WATER / ISOPROPANOL (10%). EXPERIMENTALLY gets ARE EXCELLENT PERFORMANCE, AND PARTICIPATE IN THE PREPARATION OF A TEST FOR ACTION (BENCHMARK) EXPERIMENTAL CONJUNCTION WITH UNIVERSITIES MONS-HAINAUT (BERLGICA), OF BAYREUTH (GERMANY), DE TOULOUSE (FRANCE) AND MAX-PLANCK INSTITUTE OF MAINZ (GERMANY).
2 tesis en 1 páginas: 1
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